This video shows how to paint the face and horns on Sigvald the Magnificent from the Hedonites of Slaanesh by Games Workshop.
The following paints were used:
Games Workshop: Cadian Fleshtone (Kislev Flesh and Ushabti Bone optional), Daemonette Hide, Temple Guard Blue, Mephoston Red, Balor Brown, Morghast Bone, Ushabti Bone, Screaming Skull, Rhinox Hide
Vallejo: Pale Grey Blue, Black
P3: Morrow White