An organic chemistry minilecture on the Enantioselective Total Synthesis of Dysiherbols A, C, and D by Shengkun Hu and Yefeng Tang*. It utilizes a highly unusual [1,2]-Anionic Rearrangement / Cyclopropane Fragmentation reaction to form the dysiherbol framework that can be easily functionalized to synthesize multiple members of this family.
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NMR Spectroscopy in music:
J. New Music Res. 2021, 50:5, 487-501
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References:
J. Am. Chem. Soc. 2022, 144, 19521−19531 (This work)
J. Nat. Prod. 2016, 79, 2, 406–411 (Discovery)
Chin. J. Nat. Med. 2022, 20, 148-154 (Discovery)
Angew. Chem., Int. Ed. 2021, 60, 13807−13813 (Previous synthesis/ Structural revision)
Angew. Chem., Int. Ed. 2021, 60, 14915−14920 (Previous synthesis/ Structural revision)
Theoret. Chim. Acta , 1977, 45, 283–300 (Quinone- alkene photocycloadditions)
Tetrahedron Lett. 1988, 29,2761−2764 (Alkene isomerisation)
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