An organic chemistry minilecture on the ’Enantioselective Total Synthesis of (−)-Caulamidine A’ by Zhouyang Zhu and Thomas J. Maimone* It features an asymmetric prenylation, doubled displacement annulation and adiastereoselective Hydrogen Atom Transfer reaction.
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References:
J. Am. Chem. Soc. 2023, 145, 14215−14220 (This work)
. Prod. 2004, 67, 70−73 (Isolation)
Chem. Sci. 2018, 9, 307−314 (Complete characterization)
Nat. Catal. 2018, 1, 601−608 (Prenylation)
Tetrahedron Lett. 2010, 51,3879−3882 (Amidation)
Tetrahedron 2017, 73, 4233–4258 (Ozonolysis)
J. Am. Chem. Soc. 2014, 136, 4, 1300–1303 (Mn Reduction)
J. Am. Chem. Soc. 2014, 136, 6884−6887(Mn Reduction)
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